If your site is one of the 12 million domains using the PHP scripting language, then PHP.net is a good place to find PHP related information. Links to resource sites, tutorials, manuals, books and much more.
ScriptWiz.com Offers hundreds of free and commercial scripts to improve your website. The site also offers tutorials as well as a breakdown of scripts by date, most popular and top ranked.
ScriptsFinder.com Offers hundreds of free and commercial scripts to improve your website.
Zvon.org Covers different aspects of XML, ranging from a basic introduction to programming references and advanced tutorials. A good place to learn more about the versatility of XML.